Oily water/ waste water treatment is a crucial process for industries like oil and gas, petrochemical, automotive, and food processing, where water contaminated with oil needs to be treated before being discharged or reused. The treatment process involves several stages to remove oil, grease, and other contaminants effectively. Here is an overview of the main methods and technologies used:
1. Primary Treatment: Physical Separation
- Gravity Separation: Uses gravity to separate oil and water due to their different densities. Equipment like oil-water separators (API separators, CPI separators) are used.
- Coalescence: Uses coalescing filters or plates to aggregate small oil droplets into larger ones that rise to the surface more easily.
- Skimming: Involves skimmers that remove floating oil from the surface of the water.
2. Secondary Treatment: Chemical and Biological Processes
- Chemical Treatment:
- Flocculation and Coagulation: Chemicals (coagulants and flocculants) are added to the water to aggregate fine oil droplets and suspended particles into larger particles that can be removed easily.
- Dissolved Air Flotation (DAF): Involves the injection of air bubbles to which oil droplets and other contaminants adhere, floating to the surface for removal.
- Biological Treatment:
- Aerobic Treatment: Uses microorganisms that consume organic matter (including some oil components) in the presence of oxygen.
- Anaerobic Treatment: Utilizes microorganisms that function in the absence of oxygen to break down organic matter, producing methane and carbon dioxide.
3. Tertiary Treatment: Advanced and Polishing Steps
- Filtration: Removes remaining suspended solids and fine oil droplets using sand filters, multimedia filters, or membrane filters.
- Adsorption: Utilizes materials like activated carbon to adsorb residual oils and other organic contaminants from the water.
- Advanced Oxidation Processes (AOPs): Uses chemical oxidants like ozone, hydrogen peroxide, or UV light to break down remaining organic pollutants.
- Membrane Technologies: Ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO) for fine and ultrafine removal of contaminants.
4. Sludge Treatment and Disposal
- The sludge generated from the treatment processes, containing concentrated oil and other contaminants, must be treated and disposed of properly. This might involve dewatering, incineration, or landfill disposal following environmental regulations.
Key Technologies and Equipment
- API Separators: Designed to separate large quantities of oil and suspended solids based on gravity.
- CPI Separators (Corrugated Plate Interceptors): Similar to API separators but with corrugated plates to improve oil-water separation.
- DAF Units: Equipment designed to carry out dissolved air flotation.
- Coalescers: Devices that use coalescing media to facilitate the aggregation of small oil droplets.
- Activated Carbon Filters: Used for adsorption of residual organic contaminants.
- Membrane Systems: Used in various stages for fine and ultrafine filtration.
Considerations and Regulations
- Regulatory Compliance: The treated water must meet regulatory standards for discharge or reuse, which can vary by region and industry.
- Environmental Impact: Proper treatment minimizes the environmental impact of discharging oily wastewater, protecting aquatic life and water quality.
- Cost and Efficiency: The selection of treatment processes must balance cost, efficiency, and the specific requirements of the wastewater being treated.
In summary, oily wastewater treatment is a complex process involving a combination of physical, chemical, and biological methods to remove oil and other contaminants. The goal is to produce water that meets regulatory standards for discharge or reuse, while also managing the resulting sludge in an environmentally responsible manner.